New PDF release: Advances in Biomimetics

By Anne George

ISBN-10: 9533071915

ISBN-13: 9789533071916

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1994). Application of hydroxyapatite-sol as drug carrier. Biomed. Mater. , 4, 283-90. ; Berman, R. ; et al. (2003). DNA-templated carbon nanotube field-effect transistor, Science, 302, 1380. Kim, H. ; Lee, H. ; Knowles, J. C. (2006). Electrospinning biomedical nanocomposite fibers of hydroxyapaite/poly(lactic acid) for bone regeneration. J. Biomed. Mater. Res. Part A, 79A, 643-9. Kim, H. ; Knowles, J. C. & Kim, H. E. (2004). Hydroxyapatite/poly (epsilon-caprolactone) composite coatings on hydroxyapatite porous bone scaffold for drug delivery.

SEM micrographs of samples prepared using different CO32– source and basic additive in EG by microwave heating for 20 min (except (j) for 1 h). (a,c,e,g,i) using (NH4)2CO3 as the CO32– source at 130 oC (except (c) at 150 oC); (b,d,f,h,j) using Na2CO3 as the CO32– source at 180 oC. (a,b) without an basic additive, (a) shows pumpkin-like morphology of aragonite phase of CaCO3, the insets of (a) show typical pumpkin-like morphology, scale bar = 200 nm, (b) shows cuboid-like morphology of calcite phase; (c,d) using urea, (c) shows a typical olive-like morphology of the aragonite phase, the inset of (c) shows a typical olivelike morphology, scale bar = 200 nm, (d) TEM micrograph showing the porous willow-leaflike morphology of the aragonite phase; (e,f) using hexamethylenetetramine (HMT), (e) shows a sphere-like morphology assembled from nanoparticles of the vaterite phase, the inset of (e) shows a typical assembled sphere, (f) shows cuboid-like morphology of calcite; (g,h) using ethylenediamine (EDA), (g) shows spherical nanoparticles of amorphous phase of CaCO3, (h) shows flower-like morphology of aragonite; (i,j) using NaOH, (i) shows the flake congeries of the vaterite phase, (j) shows cauliflower-like morphology of the calcite phase.

The microwave heating leads to a high heating rate and a rapid increase in temperature during the nucleation process, which is important for fast nucleation and growth of crystals. The rapidly changing electric field of the microwave reactor induced the oriented self-assembly of SrCO3 nanocrystals. The self-assembly of nanocrystals depends on the interparticle interactions, crystal size distribution and shape. The microwave heating favored the formation of nanoparticles with a narrow size distribution.

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Advances in Biomimetics by Anne George

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